Serial number dates to 1969 - so obviously is early.
I don't know when the deployant was first introduced, but have never seen it on anything close to this early.
I'm glad to hear that you want to stay true to Breitling parts, but you will find that BUSA no longer do the work themselves. They'll refer you to Mark Heist at Horological Services -
http://www.horologicalservices.com/Some of the best work that I have ever seen, with appropriate prices, and an approximately 1 year waiting list.
Don't know of any of the 100 years of flight Navis - I knew of a NOS Montbrillant 100 years (the one year special edition) last year which may still be available, but the others are rarer than hens' teeth.
Most importantly - welcome to BreitlingSource.